trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
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منابع مشابه
trans-Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate
In the title compound, [RuCl(2)(C(4)H(4)N(2))(4)]·2CH(2)Cl(2), the Ru(II) atom occupies a position of 222 symmetry and the C atom of the solvent mol-ecule occupies a site with twofold symmetry. The Ru(II) atom has a slightly distorted octa-hedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN(4) plane. In the crystal, the complex and solvent mol-ecules are br...
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In the title compound, [PtI(2)(C(5)H(5)NO)(2)]·2(CH(3))(2)SO, the Pt(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment by two trans iodide ligands and two pyridine N atoms. In the crystal, complex mol-ecules and solvent dimethyl sulfoxide mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds.
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In the title compound, {[Ni(C10H8N4)2(H2O)2]I2·2C2H5OH} n , the complex shows an octa-hedral environment of the Ni(2+) cation in which it is located on a centre of symmetry, linked to two water mol-ecules and the pyridine-N atoms of four 4,4'-(diazenediyl)dipyridine ligands bridging Ni(2+) cations along the b- and c-axis directions, giving rise to a two-dimensional arrangement. The Ni-N bond le...
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was obtained from the reaction of Pd(PPh3)4 with Me3SiCN (1:1 molar ratio) in benzene (at 80 ̊C for 2 h). Crystals suitable for X-ray diffraction analysis were obtained by recrystallization from a mixture of CH2Cl2 and C6H6 (ca. 1:4 by volume). Table 1 summarizes the crystal and experimental data. During the data collection at room temperature, decay was not observed. All intensity data were cor...
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In the title compound, [V(C15H11O2)2O(CH3OH)]·2CH3OH, the V(IV) atom is coordinated by two 1,3-diphenyl-propane-1,3-dionate ligands and an oxide ligand in an axial position. The sixth position is occupied by the O atom of a methanol group bonded trans to the oxide atom. The octa-hedral geometry is significantly distorted, with the V(IV) atom lying 0.330 (3) Å above the equatorial plane formed b...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812035817